<p>I took the plunge and bought a resin printer. I was wondering if I could use full strength home-brew vodka at 90 % instead of using isopropyl alcohol before anything is added to clean prints with?</p>
<p>I cannot seem to find anywhere or anyone that has tried this.</p>

Isopropyl-Alcohol - Propan-2-ol - and Ethyl alcohol - Ethan-1-ol - are different chemically. As a secondary alcohol, Propan-2-ol has quite different solubility of different materials than ethyl-alcohol.
Now, let's look at home made alcoholic destillate. That stuff is, if done in one refraction and without tossing the first low temperature part, some percentages Metanol, Ethyl alcohol and maybe some water. That has not the same solvent properties as Propan-2-ol.
While it
might
work, nobody will sign a guarantee that it doesn't negatively impact your print.