<p>I'm new to the VxWorks Environment are there any good sources of information out there? </p>

If your budget allows it, I would recommend taking one of the courses offered by WindRiver.  My company brought in one of their trainers to teach a class on-site and it was excellent.  They provided hands-on programming activities and a lot of information.  If you are new to the concepts of real-time or embedded programming, they provided the necessary background information, and even if you were already familiar with these (as I was), there was plenty of useful training specific to VxWorks and Workbench.  I believe they also organize their own courses, in addition to coming to companies.
Course Schedule